First of all you have to create a vlan which will be only used for carrying the RSPAN traffic.Create a dedicated vlan on both the switches:
Conf t
vlan xx
remote-span
On the source switch i.e 6506 you have to run the following command:
conf t
monitor session 1 source < Define the interfaces or source vlan that you want to monitor>
monitor session 1 destination remote vlan xxx
On you destination switch i.e 3750:
conf t
monitor session 1 source vlan xxx
monitor session 1 destination interface fa X/x -> port connected to the monitoring server.
Please use the link below for more info:
http://www.cisco.com/univercd/cc/td/doc/product/lan/cat6000/122sx/swcg/span.htm
http://www.cisco.com/univercd/cc/td/doc/product/lan/cat3750/12235se/scg/swspan.htm
HTH,Please rate if it does.
-amit singh