Assuming UCCX, and that you mean controlling the 'Not Ready on No Answer' setting - no, there is no way.
In your scenario this is good, as it means that the department that want Not Ready turning off will have to learn to use the system properly! It's always a bad idea to turn it off. If they're really keen, give them a hunt group instead :-)
If you just mean the amount of time that the agents are given to answer a call, you can control this on the 'select resource' step.
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