bcc is not a 'header'. It is actually, the specific lack of a header.
When a message is addressed to an envelope recipient without the To: header (or any other header) showing the address, that is a bcc. It is used for many legitimate purposes where recipients don't need to know who else recieved that message. It's very commonly used in mailing lists. And of course, abused in many inventive ways.
To capture that with a filter, you might want to test that the envelope recipient was in the To: header, and NOT quarantine that, but quarantine everything else.
Something like this may work.
if (rcpt-to == $Header['To'])
{
deliver();
}
else
{
duplicate-quarantine('Policy');
}
I haven't tested it, so YMMV.