Export directly in xls, xlsx or pdf - no.
The output of "show run interface" or "show interface" is pretty structured however and easily parsed by Excel - either manually or via a macro. See output below (you can omit the interface identifier to get all interfaces. I used one for brevity.)
One can build a script to log in, perform an arbitrary command logging the output to a file which can then be massaged to extract the information you want in a suitable format (csv, etc.). Once in Excel it can be saved as pdf if you're so inclined.
Of couse, some of the full-featured network management tools do a lot of this (and lots more) if you have them.
ASA-1# sh run int eth0/0
!
interface Ethernet0/0
nameif outside
security-level 0
ip address x.x.x.x 255.255.255.224
ASA-1#
ASA-1# sh int eth0/0
Interface Ethernet0/0 "outside", is up, line protocol is up
Hardware is i82546GB rev03, BW 1000 Mbps, DLY 10 usec
Auto-Duplex(Full-duplex), Auto-Speed(1000 Mbps)
Input flow control is unsupported, output flow control is unsupported
MAC address 0013.c480.6b50, MTU 1500
IP address x.x.x.x, subnet mask 255.255.255.224
14156274 packets input, 16095096189 bytes, 0 no buffer
Received 44764 broadcasts, 0 runts, 0 giants
0 input errors, 0 CRC, 0 frame, 0 overrun, 0 ignored, 0 abort
0 pause input, 0 resume input
0 L2 decode drops
8548524 packets output, 1006461151 bytes, 0 underruns
0 pause output, 0 resume output
0 output errors, 64 collisions, 6 interface resets
95 late collisions, 627 deferred
0 input reset drops, 0 output reset drops, 0 tx hangs
input queue (blocks free curr/low): hardware (255/230)
output queue (blocks free curr/low): hardware (255/125)
Traffic Statistics for "outside":
14156267 packets input, 15839536990 bytes
8548619 packets output, 820243613 bytes
39502 packets dropped
1 minute input rate 2 pkts/sec, 349 bytes/sec
1 minute output rate 2 pkts/sec, 425 bytes/sec
1 minute drop rate, 0 pkts/sec
5 minute input rate 2 pkts/sec, 2091 bytes/sec
5 minute output rate 1 pkts/sec, 352 bytes/sec
5 minute drop rate, 0 pkts/sec
