QoS ACLs,Cisco IOS ACLs ,VACLs are the ACL'S supported by 6500 series switches.
MAC ACL'S can be used to filter based on the MAC address in 6509 switches.
Command to be use for configuring MAC ACL:
set qos acl mac acl_name {dscp dscp | trust-cos} [aggregate aggregate_name] src_mac_spec dest_mac_spec [ethertype] [before editbuffer_index | modify editbuffer_index]