You can get a good idea by doing :
'show platform software int '
It will show you something like this:
show platform software interface
Switch Phyport Gi1/1 Non-Zero Software Statistics
TxBytesTxQ1 : 1192020
TxBytesTxQ3 : 11421
RxIslTaggedPackets : 3002
RxBcastAndOrMcastBytes : 8589934592
Then you can check which DSCP values go to which TX queue:
show qos map dscp to tx-queue.
I also believe it will show you Rx and Tx packets with their CoS values as well if L2. I don't have a 4500 on me at the moment, but will update this when i get one to confirm