Blocking Instant Messaging and Peer-To-Peer File Sharing Applications
http://www.cisco.com/en/US/products/sw/iosswrel/ps5207/products_white_paper0900aecd802efa46.shtml
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Blocking Peer-to-Peer File Sharing Programs with the PIX Firewall
http://www.cisco.com/en/US/products/hw/vpndevc/ps2030/products_tech_note09186a00801e419a.shtml
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If you are running version 7 of the Pix software, you have more options to stop IM traffic.
Introduces new inspection services to detect and optionally block instant messaging, peer-to-peer file sharing, and other applications tunneling through Web application ports
Blocks popular instant messaging applications such as AOL Instant Messenger, Microsoft Messenger, and Yahoo Messenger
Stops peer-to-peer file sharing applications such as KaZaA and Gnutella
Thwarts tunneling applications such as GoToMyPC
http://www.cisco.com/en/US/products/hw/vpndevc/ps2030/products_data_sheet0900aecd80225ae1.html