IF the routers are all connected via the inside interface of the PIX, then they should be able to access DMZ resources in the same fashion that users directly connected to the inside interface can. If they cannot:
1. there could be a routing problem with those 2 routers - they might need a static route to be able to talk to the dmz.
2. there could be an access-list bound to the dmz interface of the pix that limits what traffic the dmz hosts can send through the pix - this could be limited to the ip block used by the directly connected inside interface hosts.
I would check both the pix config, and test for routing issues. I would look at what services should be available to those users, and test at each network hop.
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We have configured the outside and inside Interface with official ipv6 adresses, set a default route on outside Interface to our router, we also have definied a rule , which also gets hits, to permit tcp from inside Interface to any6.
In Syslog I also se...