Kalpesh-
Let's say that the DMZ is 10.0.0.0 /24 and your Inside network is 192.168.1.0 /24. Lastly, the DHCP scope for your VPN clients is 192.168.100.0 /24.
You would need to have two NAT statements in order for the VPN users to reach both networks:
nat(dmz) 0 access-list DMZNONAT
nat (inside) 0 access-list INSIDENONAT
(or whatever you want to call the ACLs)
Then, setup your access-lists:
access-list INSIDENONAT extended permit ip 192.168.100.0 255.255.255.0 192.168.1.0 255.255.255.0
access-list DMZNONAT extended permit ip 192.168.100.0 255.255.255.0 10.0.0.0 255.255.255.0
If you are using split-tunneling you will need to add a line to the split-tunnel ACL for your inside network as well:
access-list SPLIT-TUNNEL standard permit 192.168.1.0 255.255.255.0
That should do it.
HTH,
Paul