You probably changed the nat 0 access-list to only reference the IPSec pool of addresses.
Let's say you have this:
ip local pool pptppool 10.1.1.1-10.1.1.254
ip local pool ipsecpool 10.2.2.1-10.2.2.254
and your inside network is 192.168.1.0/24. Your PIX config needs to look like this:
nat (inside) 0 access-list nonat
access-list nonat permit ip 192.168.1.0 255.255.255.0 10.1.1.0 255.255.255.0
access-list nonat permit ip 192.168.1.0 255.255.255.0 10.2.2.0 255.255.255.0
In short, make sure both your IP pools (for the PPTP and IPSec users) are included in the nat 0 access-list.